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水基共聚物-生物炭复合材料包膜缓释氮肥制备及氮素在土壤-作物系统中化学行为

水基共聚物-生物炭复合材料包膜缓释氮肥制备及氮素在土壤-作物系统中化学行为
  • 导航:首页 > 科学基金
  • 批准号:31572206
  • 批准年度: 2015年
  • 学科分类:肥料与施肥(C1509) |
  • 项目负责人:邹洪涛
  • 负责人职称:教授
  • 依托单位:沈阳农业大学
  • 资助金额:59万元
  • 项目类别:面上项目
  • 研究期限:2016年01月01日 至 2019年12月31日
  • 中文关键词: 共聚物;复合材料;氮素;土壤;作物
  • 英文关键词:Slow release fertilizer;New type of material;Nutrient behavior;Slow release mechanism

项目摘要

中文摘要

包膜缓释氮肥能够提高氮率利用率,减少氮肥施用对环境造成的负面影响而受到广泛关注。缓控释效果好、价格低廉、环境友好的膜材料研发已成为包膜缓释肥料领域研究热点。本项目采用有机高分子聚合和溶液共混技术以成膜性好、可降解的聚乙烯醇、聚乙烯吡咯烷酮共聚物为成膜剂,以比表面积大、吸附性强的生物炭为填充物制成水基共聚物-生物炭复合膜材料,通过测定膜材料疏水性、力学特性、微形态等指标明确各组分适宜配比和合成条件;采用流化床工艺对颗粒尿素(15N标记)进行包膜,制备包膜缓释氮肥。利用红外光谱仪和扫描电镜技术结合养分溶出特征,明确该膜材料对养分控释机理;采用土箱微区的试验方法,利用15N稳定性同位素示踪技术阐明所研制的新型包膜缓释氮肥氮素在土壤-作物系统中迁移转化规律,揭示该包膜缓释氮肥提高氮素利用效率的机理。研究结果为价格低廉、环境友好、养分控释效果好的包膜缓释肥料研发和应用提供科学依据。

英文摘要

Coated nitrogen attracted extensive attention worldwide since it can improve nitrogen use efficiency and reduce the negative impact of nitrogen applying on the environment. The research and development of membrane material which is inexpensive, environment friendly, nutrient release effectively has become a hot topic in the field of coated slow-release fertilizer. .The copolymer of polyvinyl alcohol which is easy to be filmed and biodegradable and polyvinylpyrrolidone will be used as film-formed agent by the technologies of organic polymer polymerization and solution blending. Biochar which has big surface area and high adsorption capacity will be used as stuffing to produce aqueous copolymer/biochar composites. The suitable ratio of all fractions and synthesis conditions will be determined by measuring hydrophobicity, mechanical property and micromorphology etc. of membrane. Granular urea (15N labeled) will be coated using fluidized bed process to produce slow-release fertilizer. The nutrients releasing mechanisms of this membrane will be confirmed using infrared spectroscopy and scanning electron microscopy combined with nutrient dissolution characteristics. Meanwhile, the increasing of nitrogen use efficiency of coated slow-release fertilizer will be also clarified in this study. These results will provide the scientific basis for the research-development and apply of coated slow-release fertilizer, which has characteristics of inexpensive, environment friendly and nutrient release effectively.

评估说明

    国家自然科学基金项目“水基共聚物-生物炭复合材料包膜缓释氮肥制备及氮素在土壤-作物系统中化学行为”发布于爱科学iikx,并永久归类于相关科学基金导航中,仅供广大科研工作者查询、学习、选题参考。国科金是根据国家发展科学技术的方针、政策和规划,以及科学技术发展方向,面向全国资助基础研究和应用研究,发挥着促进我国基础研究源头创新的作用。国科金的真正价值在于它能否为科学进步和社会发展带来积极的影响。

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